Steve doesn't get mistaken for many people back where he's from, so if he knew what was on her mind he might think of it as a refreshing change of pace. If he knew who Oliver Queen was, on the other hand -- well, it's just a good thing they're both walking into this a little blind.

Even without the added nicety, Steve still would have rose to his feet and politely offered to pull out a chair for her. Maybe she'll think it's presumptuous of him, but it's not exactly meant as an invitation to join him so much as it is for what he's about to say she might want to be sitting.

"Of course. You're on the Enterprise," he says, rubbing the back of his neck. "The, uh. Starship Enterprise."